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Manganese Sulphate or Manganese Sulfate Monohydrate Tetrahydrate Anhydrous SDS GHS of Manufacturers
CAS Number Monohydrate 10034-96-5, EC Code EINECS 232-089-9, Molecular Weight 169.02, Chemical Formula: MnSO4-H2O
Specifications Sheet of Manganese Sulfate Suppliers
Manganese Sulfate or Manganese Sulphate SDS, Safety Data Sheet
MSDS
Section 1. Product Information
Product Name & Other Names: Manganese Sulfate or Manganese Sulphate.
manganese sulfate forms a variety of hydrates: monohydrate, tetrahydrate, pentahydrate, and heptahydrate. The monohydrate is most common.
Synonym: Sulfuric Acid, Manganese salt monohydrate, Manganous Sulphate
Formula: MnSO4-H2O, MnSO4
Chemical Name: Manganese Sulfate Monohydrate
Chemical Formula: MnSO4-H2O for monohydrate
CAS No.: 10034-96-5 (monohydrate) 7785-87-7 (anhydrous)
EINECS EC Number: 232-089-9
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Specific target organ toxicity, single exposure; Respiratory tract irritation (Category 3), H335
Specific target organ toxicity - repeated exposure (Category 2), H373
Acute aquatic toxicity (Category 2), H401
Labelling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Marine Pollutant |
GHS Label Elements |
Signal Words: Warning
Hazard statements:
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
H401: Toxic to aquatic life.
Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P312: IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
N = Dangerous for the environment.
Xn = Harmful.
Xi = Irritant.
Risk Phrases:
R37 Irritating to respiratory system.
R48 Danger of serious damage to health by prolonged exposure.
R51= Toxic to aquatic organisms.
Section 3: Composition and Information on Ingredients
Product Name & Other Names: Manganese Sulfate monohydrate or Manganese Sulphate monohydrate.
Synonym: Sulfuric Acid, Manganese salt monohydrate, Manganous Sulphate
CAS No.: 10034-96-5; 98-100% by Weight.
EINECS EC Number: 232-089-9
Section 4. First Aid & Procedure
Always get medical attention after the first aid is over.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation: Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.
Section 5. Fire Fighting Measures
Flash Point: N/A
Auto ignition Temperature: N/A
Extinguishing Medium: Water fog or other medium appropriate to surrounding fire conditions.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire. The use of fire extinguishers of the chlorinated hydrocarbon type is not recommended, as toxic products will probably be produced by the decomposition of the extinguishing medium when it encounters hot manganese compounds.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
Section 6. Spills and Disposals
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Pick up and arrange disposal without creating dust. Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.
Section 7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents, strong acids, aluminum, and magnesium.
Section 8. Exposure Controls & Personal Protection
Exposure Limits:.
OSHA PEL: 5mg/COM Ceiling for manganese compounds as Mn.
ACGIH TLV: 0.2 mg/CBM (TWA) for manganese, elemental and inorganic compounds as Mn. Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area.
Section 9. Physical & Chemical Data
Appearance: Solid. Slightly pink powder.
Odor: Odorless
Odor threshold: Not available.
pH Value: 4.0 - 7.0
Relative density: around 2.95
Melting Point: 2000C.
Boiling Point: 8500C.
Flash point: Not available.
Decomposition: 2000C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Easily soluble in water, insoluble in ethanol.
Viscosity: Not available.
Section 10. Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Incompatibility (Materials to Avoid): Strong oxidizing agents, strong acids, aluminum and magnesium.
Conditions to Avoid: Incompatible materials, exposure to moist air or water, excessive heat.
Hazardous Decomposition Products: Carbon dioxide, sulfur oxides, oxides of manganese.
Hazardous Polymerization: Will not occur.
Section 11. Toxicological Information
Toxicity to Animals: LD50/LC50, N/A. Oral (Rat) 2150mg/kg. Does not belong to toxic substances.
Carcinogenicity: Not listed as a suspected/confirmed carcinogen by ACGIH, IARC, NTP, SHA.
Mutagenic: Possible for humans. Laboratory experiments have shown mutagenic effects.
Reproductive Toxicity: May damage the reproductive system.
Teratogenic: Teratogenic effects shown in lab animals.
Section 12. Ecological Information
Toxicity to fish: No data found.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Section 13. Disposal Suggestions
Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.
Section 14. Transport and Label Information
DOT USA & TDG Canada: Not dangerous goods
IMDG/IMO:
UN number: 3077; Class: 9; Packing group: III; EMS-No: F-A, S-F
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Manganese Sulfate Monohydrate)
IATA/ICAO:
UN number: 3077; Class: 9; Packing group: III;
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Manganese Sulfate Monohydrate)
ADR/RID Europe:
UN number: 3077; Class: 9; Packing group: III;
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Manganese Sulfate Monohydrate)
Section 15. Regulatory Information
USA:
OSHA Hazards: No known OSHA hazards.
SARA 311/312: See section2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Section 16. Other Information
European Labeling in Accordance with EC Directives:
H335 = May cause respiratory irritation.
H373 = May cause damage to organs through prolonged or repeated exposure.
H401 = Toxic to aquatic life.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Manganese Sulphate or Manganese Sulfate Monohydrate Tetrahydrate Anhydrous FCC Food Reagent BP Ph Eur Grade Manufacturers
Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264
e-mail: anmolc@mtnl.net.in
Exports to USA, Canada, UAE, Dubai, South Africa, Tanzania, Kenya, Nigeria, Egypt, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Europe Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Vietnam, Korea, Japan, etc.
Copyright and Usual Disclaimer is Applicable. 23 January, 2022